ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2026
High-Performance Ternary Organic Solar Cells via Isomeric Engineering of Nonfullerene Guest Acceptors.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Constructing ternary blends has been considered as a feasible approach to achieve highly efficient organic solar cells; however, the delicate choice of the guest components still needs labor-intensive and time-consuming work. Herein, the isomeric effects of guest nonfullerene acceptor on the physicochemical and photovoltaic properties of ternary OSCs are systematically investigated. Two isomeric NFAs, BTP-γ-Br and BTP-δ-Br, with different bromine-substituted sites on IC terminal groups were designed and synthesized. BTP-δ-Br exhibits a larger dipole moment with red-shifted absorption and tends to form overagglomerations with strong self-aggregation behavior, while BTP-γ-Br shows weaker crystallinity with face-on molecular orientation. The single crystal of BTP-γ-Br revealed that a special C≡N…H noncovalent interaction between the adjacent molecules can enhance intermolecular interactions. The D18:BTP-γ-Br-based binary OSCs delivered a reduced nonradiative energy loss (0.18 eV) and a high V
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