Sources of Heavy Metals and Their Effects on Distribution at the Sediment-Water Interface of the Yellow Sea Shelf off Northern Jiangsu.

To investigate the distribution, sources, and partitioning of heavy metals at the sediment-water interface in the northern Jiangsu coastal waters, seawater and sediment samples were collected from 24 stations east of Yanwei Port in April 2021. The concentrations of seven heavy metals (Cu, Pb, Zn, Cd, Cr, Hg, and As) and environmental parameters were determined. Methods including principal component analysis (PCA), random forest (RF), positive matrix factorization (PMF), the partition coefficient (Kp), and the source-specific partition coefficient (S-Kp) were applied. The results showed the following: (1) The overall concentration order was Zn > Cu > As > Pb > Cd > Hg in seawater and Zn > Cr > Cu > Pb > As > Hg > Cd in sediments, with Cd and Pb characterized by high spatial variability. (2) PCA and RF indicated that dissolved heavy metals were mainly influenced by dissolved oxygen, petroleum, phosphate, and dissolved inorganic nitrogen, with DIN playing a common dominant role. PMF revealed three main sources for sediment metals: agricultural (contributing notably to Cu and Zn), traffic and industrial exhaust (dominating Pb, Cr, and Hg inputs), and industrial (primarily affecting Cd, Cr, and Pb). (3) Kp analysis suggested that Pb, As, and Cu were readily adsorbed by sediments, while Cd, Hg, and Zn tended to remain dissolved. Critically, S-Kp demonstrated source dependent partitioning: Pb derived from industrial sources was almost entirely associated with sediments, while Cu and Zn originating from traffic and industrial exhaust emissions were predominantly present in the aqueous phase, and Cu and Pb derived from agricultural sources were largely deposited in sediments. These findings provide a scientific basis for heavy metal pollution control in the region.