ArticleGels (Basel, Switzerland)2026
Preparation and Thermal Safety of Ammonium Polyphosphate Doping Silica Aerogels: Effects of Content and Polymerization.
Article in Gels (Basel, Switzerland), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Hydrophobic silica aerogels (SAs) have attracted much attention because of their excellent thermal insulation performance and have potential applications in energy conservation and emission reduction. However, the organic groups on its surface are flammable, which brings security risks and limits its application scope. In this study, two kinds of ammonium polyphosphate (APP) with different polymerization degrees, namely low-polymerization-degree APP (LAPP) and high-polymerization-degree APP (HAPP), were introduced into SA to prepare APP/SA composites, to improve the thermal safety of the materials. The results showed that APP with two polymerization degrees significantly delayed the initial decomposition and peak temperature of heat flow, and HAPP reduced the gross calorific value by 31.01% at most, which is 29.04% greater than that of LAPP, indicating that the effect of HAPP was slightly better than that of LAPP. With the increase in APP with two polymerization degrees, the density increased and the porosity decreased: LAPP system was 0.095-0.196 g/cm
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