Evidence map›Paper›PMID 41737696›Full record

ArticleChemical science2026

Metal-ligand covalency of C-H activating iridium complexes from L-edge valence-to-core resonant inelastic X-ray scattering.

Raphael M Jay, Ambar Banerjee, Marco Reinhard, Huan Zhao, Nils Huse, Kelly J Gaffney, Thomas Kroll, Dimosthenis Sokaras, Philippe Wernet

Abstract read
In one paragraph

Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Raphael M JayDepartment of Physics and Astronomy, Uppsala University 75120 Uppsala Sweden raphael.jay@physics.uu.se philippe.wernet@physics.uu.se.ORCID https://orcid.org/0000-0001-9607-8264
Ambar BanerjeeResearch Institute for Sustainable Energy (RISE), TCG Centres for Research and Education in Science and Technology (TCG-CREST) Kolkata 700091 India ambar.banerjee@tcgcrest.org.
Marco ReinhardStanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory Menlo Park California 94025 USA.
Huan ZhaoCenter for Free-Electron Laser Science, Department of Physics, University of Hamburg 22761 Hamburg Germany.
Nils HuseCenter for Free-Electron Laser Science, Department of Physics, University of Hamburg 22761 Hamburg Germany.ORCID https://orcid.org/0000-0002-3281-7600
Kelly J GaffneyStanford PULSE Institute, SLAC National Accelerator Laboratory Menlo Park California 94025 USA.ORCID https://orcid.org/0000-0002-0525-6465
Thomas KrollStanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory Menlo Park California 94025 USA.
Dimosthenis SokarasStanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory Menlo Park California 94025 USA.
Philippe WernetDepartment of Physics and Astronomy, Uppsala University 75120 Uppsala Sweden raphael.jay@physics.uu.se philippe.wernet@physics.uu.se.ORCID https://orcid.org/0000-0001-7011-9072

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The electronic structure of iridium carbonyl complexes is known to be fundamental to their ability to activate alkane C-H bonds following UV photolysis. Here, we investigate three prototypical iridium complexes with different ancillary ligands using valence-to-core resonant inelastic X-ray scattering measurements at the Ir L

Identifiers

PMID41737696
PMCPMC12927629

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.