ArticleACS earth & space chemistry2026
Yield of the Four-Carbon Stabilized Criegee Intermediates from Isoprene Ozonolysis.
Article in ACS earth & space chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Temperature-Dependent Kinetics of the Methyl Vinyl Ketone Oxide Criegee Intermediate: Self-Reaction and Reaction with Trifluoroacetic Acid.The journal of physical chemistry. A · 2026Article
- Direct measurement of Criegee intermediates in isoprene ozonolysis.Nature communications · 2026Article
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Isoprene is the single most abundant nonmethane hydrocarbon emitted into the atmosphere. Despite this, uncertainties in the oxidation chemistry remain. Here, we investigate the yields of Criegee intermediates that are produced from the ozonolysis reaction, where we conduct a series of atmospheric simulation chamber experiments in which the transient stabilized Criegee intermediates (sCIs) are titrated in the gas phase using either biacetyl or acetylpropionyl. This reaction yields a stable ketone-substituted secondary ozonide (SOZ), which was observed directly in the gas phase using a proton-transfer-reaction time-of-flight mass spectrometer operated in NH
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