ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2026
Synergistic Hydrogen-Bonding and Covalent Crosslinking in Polybenzimidazole Membranes for Wide-Temperature Anhydrous Fuel Cells.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Expanding the operational temperature range and reducing the humidity dependence of proton exchange membrane fuel cells (PEMFCs) remain critical challenges. To address these issues, we developed a dual-network architecture that integrates a thermally reinforced hydrogen-bonding matrix with an amine-anhydride covalent crosslinking framework within Tröger's Base (TB)-functionalized polybenzimidazole membranes. The covalently crosslinked TBAm-PBI-TB membrane with dual-network architecture exhibited a high phosphoric acid uptake of 469.5% with negligible leaching and achieved proton conductivities of 255.5 mS cm
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