ArticleRSC advances2026
Growth and morphological control of metastable KDP crystals using defect-free seeds.
Article in RSC advances, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Many functional crystal materials with significant practical value belong to metastable phases. However, the controllable growth of metastable crystals, compared with their thermodynamically stable crystalline phases, faces substantial technical bottlenecks, primarily attributed to their tendency to transform into their stable phases. Herein, we demonstrate that defect-free microscale seeds of a metastable phase, which possess smooth surfaces and high intrinsic two-dimensional (2D) nucleation barriers, can effectively suppress undesirable phase transformations, thereby realizing controlled growth and morphological regulation of the metastable phase. We employ a solution-seeding method to precisely determine the solubility of the metastable monoclinic phase of potassium dihydrogen phosphate (KH
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