ArticleACS energy letters2026
Pressure-Aware Operando X‑ray Methods Reveal True Mechanistic Pathways in Solid-State Batteries.
Article in ACS energy letters, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Operando studies of solid-state batteries (SSBs) must capture device-relevant stack pressure and temperature, since uncontrolled conditions can cause relaxation artifacts and lead to false mechanistic interpretations. To address this, we developed an operando framework for X-ray diffraction (XRD) and X-ray spectroscopy (XAS) with precisely controlled dynamic pressure and temperature, deployable across three platforms: (i) scanning microbeam transmission XRD for spatiotemporal mapping of reaction fronts, state-of-charge gradients, and stress localizations; (ii) coupled transmission XRD-XAS for simultaneous tracking of structural and redox evolution; and (iii) laboratory XRD for real-time monitoring of phase transformations during operation. Validated on sulfide-electrolyte SSBs with Li-In anodes and LiNi
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