ArticleNature communications2026
High Open-Circuit Voltage-Fill factor product in perovskite solar cells enabled by ferroelectric heterojunction modulation.
Article in Nature communications, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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16 authors.
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Abstract
Overcoming the inherent limitations of perovskite-perovskite heterojunctions in simultaneously boosting built-in potential and suppressing non-radiative recombination remains a critical challenge in perovskite solar cells. Here, we introduce a ferroelectric-based heterojunction architecture that addresses this dual challenge through synergistic mechanisms. Firstly, the spontaneous polarization inherent to the ferroelectric-based heterojunction significantly amplifies the built-in electric field, enhancing charge separation and transport, thereby increasing open-circuit voltage from 1.16 to 1.21 V. Secondly, ferroelectric nuclei effectively regulate perovskite crystallization kinetics via dissolution-recrystallization modulation, effectively suppressing trap states and elevating fill factor from 83.6% to 86.8%. The champion devices achieve a power conversion efficiency of 26.62% (certified 26.07%) with an open-circuit voltage-fill factor product of 1.05 V, reaching 90.3% of the Shockley-Queisser limit. Furthermore, the modified devices demonstrate enhanced operational stability with over 85% efficiency reservation after 500 h of maximum power point tracking, charting clear pathways towards high-performance photovoltaic cells.
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