ReviewBeilstein journal of organic chemistry2026
Arene activation via π-bond localization: concepts and opportunities.
Review in Beilstein journal of organic chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Dearomatization reactions of aromatic feedstocks constitute a highly efficient and conceptually powerful class of transformations for the synthesis of complex, three-dimensional molecular architectures with tailored physicochemical properties. Despite notable advances in dearomative methodologies over the past decades, the selective and controlled disruption of the aromatic core continues to represent a fundamental challenge in synthetic chemistry. In this review, we delineate the potential of π-bond localization within the aromatic framework as a general strategy for arene activation and dearomatization. Four distinct approaches are discussed, encompassing localization of the arene π-bonds through small-ring annelation as well as transition metal coordination to aromatic fragments in an η
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