ArticleAngewandte Chemie (International ed. in English)2026
Photoinduced Generation of (Boryl)Silyl and (Chloro)Silyl Radicals: Access to Trisubstituted Silylboranes and Chlorosilanes.
Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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1 citing paper in PubMed.
- Silyl Radical Formation from Silanethiols via Sulfur Atom Transfer with Phosphinites.The Journal of organic chemistry · 2026Article
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2 authors.
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Abstract
Trisubstituted silylboranes and chlorosilanes are in high demand for the precise synthesis of tetrasubstituted organosilicons. However, conventional synthetic methods often require harsh conditions and exhibit low functional-group tolerance, limiting their chemical diversity. In this study, we present a versatile photoinduced hydro(boryl)silylation and hydro(chloro)silylation of alkenes to construct trisubstituted silylboranes and chlorosilanes. This method employs the in situ generation of novel silyl radicals, such as (boryl)silyl radicals (R
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