ArticleScientific reports2026
Continuous flow hydroprocessing of waste plastics using ionic liquid catalyst.
Article in Scientific reports, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The present study attempted continuous flow hydroprocessing of waste plastics utilizing an ionic liquid-based catalyst to obtain diesel-like hydrocarbon fractions. Continuous flow processing offers higher efficiency and cost-effectiveness for commercial production. The ionic liquid (IL) improves the dispersion of active metal species and enhances mass-transfer properties, enabling efficient product formation at lower temperatures (180 °C) compared to conventional hydroprocessing catalysts (300–450 °C). The catalyst comprised of Palladium metal impregnated on mesoporous SBA-15 silica coated with 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (BMIM NTf2) ionic liquid. The reaction was performed at 180 °C and 65 bar under H2, with Weight Hourly Space Velocity maintained at 1 h⁻¹. Hydroprocessing resulted in the formation of 52.95% n-paraffins, 21.57% iso-paraffins and 25.48% aromatics as a result of hydrocracking, hydro-isomerisation and hydro-aromatization respectively. The total paraffin and aromatic content of the product (HMWPO) resulted in a 95% similarity to the commercial diesel. Also, the physicochemical properties of HMWPO aligned within EN 590 diesel standards. HMWPO was blended with commercial diesel at 10–40% volumetric ratios. The engine trials of HMWPO offered comparable combustion and emission profiles with diesel. The integrated approach of continuous processing using Pd/SBA-15/BMIM NTf2 catalysis delivered an energy efficient pathway to commercialize plastic waste to diesel like fuel.
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