ArticleACS omega2026
Hydrosilylation of Esters via a Titanocene(III) Borohydride-PMHS System: Scope, Limitations, and Mechanistic Insights.
Article in ACS omega, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Authors and funding
5 authors.
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Abstract
The hydrosilylation of aromatic and aliphatic esters using catalytic amounts of titanocene-(III) borohydride and poly-(methylhydrosiloxane) (PMHS) as the terminal reductant is described. Alcohol yields range from 43% to 99%, with select esters requiring the addition of isopropanol to promote reactivity. This modification is proposed to facilitate in situ formation of a more reactive titanocene-(III) hydride species, which appears necessary for efficient ester reduction. This ester reduction protocol is mild, cost-effective, operationally simple and has potential utility in broader reductive transformations.
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Registered trials
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