ArticleMolecules (Basel, Switzerland)2026
Releasing the Constraints on the Catalytic Performance of Ballast Stone in Co-N-C Materials.
Article in Molecules (Basel, Switzerland), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
For Co-N-C materials prepared under high-temperature calcination conditions, the formation of Co nanoparticles occurs when the metal loading exceeds 2%. Typically, CoNx is regarded as the primary active site of the catalyst, while Co nanoparticles are considered to possess limited catalytic activity. Consequently, within Co-N-C materials, Co nanoparticles are often likened to 'ballast stone' in a catalyst. In the model reaction of formic acid dehydrogenation, we incorporated boron into the precursor, thereby enhancing the electronic metal-support interactions (EMSI) between Co nanoparticles and carbon carriers. Consequently, this modification resulted in a catalytic performance of Co nanoparticles that was comparable to that of Co single-atom catalysts (SACs).
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