Tuning the Crystal Structure of Amphiphilic 3,4,5-Tris(alkyloxy)benzenesulfonates with Bulky Tetrabutylammonium Cations by Variation in the Aliphatic Chain.

Aleksei Stupnikov, Artem Bakirov, Maxim Shcherbina, Enfeng Song, Uwe Beginn, Martin Möller, Sergei Chvalun

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Article in Molecules (Basel, Switzerland), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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7 authors.

Aleksei StupnikovEnikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Science, 70 ul. Profsoyuznaya, 117393 Moscow, Russia.ORCID 0000-0003-1711-9756

Artem BakirovEnikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Science, 70 ul. Profsoyuznaya, 117393 Moscow, Russia.ORCID 0000-0003-0798-2791

Maxim ShcherbinaEnikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Science, 70 ul. Profsoyuznaya, 117393 Moscow, Russia.ORCID 0000-0002-5569-958X

Enfeng SongOrganic Materials Chemistry, Institute for Chemistry, University Osnabrück, D-49069 Osnabrück, Germany.ORCID 0009-0009-3903-552X

Uwe BeginnOrganic Materials Chemistry, Institute for Chemistry, University Osnabrück, D-49069 Osnabrück, Germany.

Martin MöllerInstitute of Technical and Macromolecular Chemistry, RWTH Aachen and DWI e.V., D-52056 Aachen, Germany.ORCID 0000-0002-5955-4185

Sergei ChvalunEnikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Science, 70 ul. Profsoyuznaya, 117393 Moscow, Russia.ORCID 0000-0001-9405-4509

Funding

Russian Science Foundation 19-73-20236

6 · The paper itself

Abstract

3,4,5-Tris(alkyloxy)benzenesulfonates constitute a class of wedge-shaped dendrons exhibiting liquid crystalline properties, characterized by a diverse and intricate phase behavior that is predominantly governed by the length of the terminal aliphatic chains and the size and nature of the dendrons' focal group, which collectively influence their self-organization. In systems comprising both two large counterions-wedge-shaped 3,4,5-tris(alkyloxy)benzenesulfonate anions and tetrabutylammonium (N(C

Indexed as

bulky focal groupsliquid crystalsoctupole organizationphase behaviorself-assemblyself-organizationwedge-shaped dendrons

Identifiers

PMID41683381

DOI10.3390/molecules31030401

PMCPMC12898579

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