ArticleRSC advances2026
Computational study of the kinetics and mechanism of radical polymerization of acrylic acid and derivatives in organic solvents.
Article in RSC advances, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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6 authors.
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Abstract
Free-radical polymerization of acrylic acid derivatives (AADs), such as acrylic acid (AA), methyl acrylate (MA), acrylamide (AM), methacrylic acid (MAA), and methyl methacrylate (MMA), proceeds through radical addition of monomers during initiation and propagation. Despite the extensive experimental literature on this process from both a radical chemistry and an industrial point of view, there is little information on the mechanistic pathways of the radical addition process, particularly in organic solvents. In this work, quantum chemical methods were applied to explore the solvent and initiator effects on AAD polymerization. The reactivity of di-
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