Entropic Control of the Helicity Inversion Rates of Twisted Metallomacrocycles by Reversible and Regioselective Deprotonation.

Tomoki Nakajima, Shohei Tashiro, Masahiro Ehara, Mitsuhiko Shionoya

Abstract read

In one paragraph

Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it

0cells of the map it votes in

0citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Tomoki NakajimaDepartment of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.

Shohei TashiroDepartment of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.ORCID 0000-0002-4706-3581

Masahiro EharaResearch Centre for Computational Science, Institute for Molecular Science, Myodaiji, Okazaki, Aichi444-8585, Japan.ORCID 0000-0002-2185-0077

Mitsuhiko ShionoyaDepartment of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.ORCID 0000-0002-9572-4620

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The rate of molecular motion has been enthalpically controlled by external stimuli such as acids and bases, electrons, and light. However, controlling the rate of molecular motion through activation entropy remains a challenging task. Here, we report entropic control of the helicity inversion rate of a trinuclear Pd

Identifiers

PMID41674014

DOI10.1021/jacs.5c18601

PMCPMC12903852

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.