ArticleRSC advances2026
Reaction yield oscillates over reaction time in first-order chemical reactions.
Article in RSC advances, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Authors and funding
6 authors.
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Abstract
The yield of a first-order chemical reaction normally has a unimodal trend over reaction time. In other words, once the population of a product decreases, it will normally never increase again by elongating the reaction time. However, in analyzing the full reaction path network of the Strecker reaction, we encountered a nontraditional behavior, where the population of an intermediate increased again after decreasing, even in a first-order reaction. Furthermore, simulations on model reaction path networks suggested that the reaction yield can oscillate multiple times over the reaction time. We mathematically prove that the number of reaction yield oscillations is at most
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