ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2026
Beyond Cartilage-Inspired Supramolecular Polyurethane for Adaptive Impact-Resistant Protection with Robustness, Self-Healing, and Recyclability.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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15 authors.
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Abstract
Conventional ceramic and metallic impact-protective materials are strong yet brittle and heavy, whereas soft materials such as Sylgard 184 and Styrofoam provide limited energy absorption and structural resilience. Achieving high impact resistance together with intrinsic self-healing and recyclability remains a long-standing challenge for polymeric systems, as most high-strength soft elastomers rely on permanent covalent networks that hinder their reprocessability. Taking inspiration from human articular cartilage-a natural impact-dissipative yet non-healable tissue-we developed a supramolecular polyurethane-urea elastomer (PU-BAMB) that emulates its fibrous-matrix architecture by integrating hierarchical hydrogen bonding and π-π stacking interactions through an aromatic diamine chain extender. This molecular design reproduces the multilevel energy-dissipation mechanism of cartilage while overcoming its biological limitation by introducing intrinsic self-healing and recyclability. The cooperative supramolecular framework achieves a finely tuned synergy between elasticity and rigidity, resulting in remarkable tensile strength (21.08 MPa), high fracture energy (138.36 kJ m
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