ArticleMikrochimica acta2026
(001)-Exposed mesoporous SnO
Article in Mikrochimica acta, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
SnO2 mesoporous nanosheets with dominant the (001) crystal planes were synthesized via a mesoporous template-confined strategy. The cetyltrimethylammonium chloride used was both the mesoporous template and structure-directing agent, which enables the SnO2 nanosheets to have a rich mesoporous structure and effectively promote the rapid diffusion of gaseous chlorine (Cl2). Meanwhile, the abundant Sn unsaturated coordination sites on the (001) planes significantly enhance Cl2 adsorption. The SnO2-(001) sensor achieved highly sensitive detection of Cl2 at room temperature. It exhibited a high response of 408 toward 5 ppm Cl2, low practical detection limit (10 ppb), excellent selectivity and long-term stability. This breakthrough not only overcomes the high-temperature working limitation of traditional SnO2-based Cl2 sensors. In addition, the sensor was employed to monitor Cl2 emissions during the use of chlorine-containing disinfectants. Test results indicated that the Cl2 concentration surpassed the safety threshold within 7-14 min of disinfectant application. It demonstrated its strong potential for practical applications. Furthermore, it lays the solid foundation for optimizing other metal oxide-based room temperature gas sensors.
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