ArticleThe journal of physical chemistry letters2026
Pyrrole without Life: Reaction of Aminomethylene with the Propargyl Radical.
Article in The journal of physical chemistry letters, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
0 citing papers in PubMed.
No citing paper in PubMed yet.
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Carbenes are reactive species found across gas-phase environments, from combustion to planetary atmospheres and interstellar space. Their reactions with radicals represent a compelling path to increasing chemical complexity, in which the formation of the first aromatic ring is a foundational step. To date, no selective gas-phase bottom-up route to the smallest nitrogen-bearing aromatic ring, pyrrole, is known. We investigated the reaction of the simplest aminocarbene, aminomethylene, with the prototypical resonance stabilized propargyl radical. Photoelectron photoion coincidence spectroscopy and semiautomated electronic structure calculations reveal a barrierless, addition-elimination mechanism producing pyrrole + H. The reaction path depends on the orientation of propargyl during the association, in which the allenyl resonance form (H
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.