Beyond Sabatier: Multiplicate Spillover Phenomena for Manipulating Catalytic Dynamics in Various Electrocatalysis.

Di Wang, Ziyou Dong, Qianqian Yao, Shixue Dou, Jun Mei, Ziqi Sun

Abstract readReview

In one paragraph

Review in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it

0cells of the map it votes in

1citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

g-CNanoscale advances · 2026
Article

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Di WangKey Laboratory for Special Functional Materials of Ministry of Education, National & Local Joint Engineering Research Center for High-efficiency Display and Lighting Technology, School of Nanoscience and Materials Engineering, Henan University, Zhengzhou, 450046, China.

Ziyou DongKey Laboratory for Special Functional Materials of Ministry of Education, National & Local Joint Engineering Research Center for High-efficiency Display and Lighting Technology, School of Nanoscience and Materials Engineering, Henan University, Zhengzhou, 450046, China.

Qianqian YaoKey Laboratory for Special Functional Materials of Ministry of Education, National & Local Joint Engineering Research Center for High-efficiency Display and Lighting Technology, School of Nanoscience and Materials Engineering, Henan University, Zhengzhou, 450046, China.

Shixue DouInstitute of Energy Materials Science, University of Shanghai for Science and Technology, 516 Jungong Road, Shanghai, 200093, China.

Jun MeiKey Laboratory for Special Functional Materials of Ministry of Education, National & Local Joint Engineering Research Center for High-efficiency Display and Lighting Technology, School of Nanoscience and Materials Engineering, Henan University, Zhengzhou, 450046, China.ORCID https://orcid.org/0000-0002-5766-0603

Ziqi SunSchool of Chemistry and Physics, Centre for Materials Science, Queensland University of Technology, 2 George Street, Brisbane, QLD, 4000, Australia.ORCID https://orcid.org/0000-0002-4777-4017

Funding

Australian Research Council DP240102728 LP230200917 IM240100202Joint Fund of Science and Technology R&D Plan of Henan Province 245200810061National Natural Science Foundation of China 52402112Natural Science Foundation of Henan Province 252300421102

6 · The paper itself

Abstract

Spillover phenomenon, which is characterized by the dynamic migration of active species across catalyst surfaces, provides a promising avenue to overcome the limitations dictated by the Sabatier principle in conventional catalysis. This comprehensive review highlights recent progress in multiplicate spillover, including hydrogen, oxygen, hydroxyl, and intermediate spillover, and their critical roles in modulating intermediate adsorption, strengthening interfacial transport, and manipulating catalytic dynamics. Then, various spillover-mediated electrocatalytic reactions, such as hydrogen and oxygen evolution, carbon dioxide and nitrogen reduction, and methanol oxidization reactions, are systematically summarized. Finally, current challenges of different spillover systems are critically assessed and future research directions are briefly outlined. It is expected that this review offers some useful guidance on rational design of high-performance spillover-based electrocatalysts and promote advancement of sustainable energy conversion technologies.

Indexed as

carbonelectrocatalysishydrogenoxygenspillover

Identifiers

PMID41632229

DOI10.1002/advs.202520177

PMCPMC12955903

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.