ArticleOrganometallics2026
Photophysical and Biological Properties of Diprotic Ruthenium(II) Complexes with Extended π-Systems.
Article in Organometallics, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Ruthenium(II) polypyridyl complexes can be harnessed for photodynamic therapy. In this work, diprotic ligands which can be deprotonated to change the metal complexes from dicationic to neutral are combined with extended π systems for light absorption at longer wavelengths. Herein, the diprotic ligands are 4,4'-dhbp = 4,4'-dihydroxybipyridine or 4,7-dhphen = 4,7-dihydroxy-1,10-phenanthroline and the π-expanded ligands are bphen = bathophenanthroline, dppz = dipyrido[3,2-a:2',3'-c]phenazine, and dppn = benzodipyrido[3,2-a:2',3'-c]phenazine. This report describes the synthesis and characterization of [(bphen)
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