Evidence map›Paper›PMID 41614159›Full record

ArticleJACS Au2026

Spectroscopically Deciphering the Formation and Reactivity of a High-Valent Ni(IV)Cl

Ayushi Awasthi, Kiran Bhadauriya, Lucia Velasco, Raju Eerlapally, Asterios Charisiadis, Rakesh Kumar, Maxime Sauvan, Dooshaye Moonshiram, Sharath Chandra Mallojjala, Apparao Draksharapu

Abstract read
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In one paragraph

Article in JACS Au, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

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Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Ayushi AwasthiSouthern Laboratories-208A, Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208016, India.
Kiran BhadauriyaSouthern Laboratories-208A, Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208016, India.
Lucia VelascoInstituto de Ciencia de Materiales de Madrid Consejo Superior de Investigaciones Científicas, Sor Juana Inés de la Cruz, 3, Madrid 28049, Spain.
Raju EerlapallySouthern Laboratories-208A, Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208016, India.
Asterios CharisiadisInstituto de Ciencia de Materiales de Madrid Consejo Superior de Investigaciones Científicas, Sor Juana Inés de la Cruz, 3, Madrid 28049, Spain.
Rakesh KumarSouthern Laboratories-208A, Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208016, India.
Maxime SauvanInstituto de Ciencia de Materiales de Madrid Consejo Superior de Investigaciones Científicas, Sor Juana Inés de la Cruz, 3, Madrid 28049, Spain.
Dooshaye MoonshiramInstituto de Ciencia de Materiales de Madrid Consejo Superior de Investigaciones Científicas, Sor Juana Inés de la Cruz, 3, Madrid 28049, Spain.ORCID https://orcid.org/0000-0002-9075-3035
Sharath Chandra MallojjalaDepartment of Chemistry, Binghamton University, Binghamton, New York 13850, United States.
Apparao DraksharapuSouthern Laboratories-208A, Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208016, India.ORCID https://orcid.org/0000-0001-7897-3230

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Recent investigations have demonstrated the appeal of using Ni-(II) complexes with redox-active ligands in fields like catalysis, electrochemistry, or materials sciences. Ni-(salen) complexes have particularly been shown to exhibit temperature-dependent equilibrium based on the localization of the unpaired spin. However, the usage of salen as a ligand has always restricted the characterization of a Ni-(IV) species with Ni bearing both the oxidizing equivalents. Hence, the current work aims to develop the biologically relevant pseudopeptide-based Ni complex that enables the formation and trapping of a high-valent Ni-(IV) species from its Ni-(II) precursor. The synthesized [LNi

Indexed as

anionic ligandshigh-valent nickeloxygen atom transferpseudopeptide ligand

Identifiers

PMID41614159
PMCPMC12848696

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.