Evidence map›Paper›PMID 41599450›Full record

ArticlePolymers2026

Sustainable Waterborne Polylactide Coatings Enabled by Hydrophobic Deep Eutectic Solvents Plasticization.

Denys Baklan, Victoria Vorobyova, Olena Sevastyanova, Taras Karavayev, Oleksiy Myronyuk

Abstract read
In one paragraph

Article in Polymers, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Denys BaklanDepartment of Chemical Technology of Composite Materials, Chemical Technology Faculty, Igor Sikorsky Kyiv Polytechnic Institute, Beresteiskyi Ave. 37, 03056 Kyiv, Ukraine.ORCID 0000-0002-6608-0117
Victoria VorobyovaPhysical Chemistry Department, Chemical Technology Faculty, Igor Sikorsky Kyiv Polytechnic Institute, Beresteiskyi Ave. 37, 03056 Kyiv, Ukraine.ORCID 0000-0001-7479-9140
Olena SevastyanovaDivision of Wood Chemistry and Pulp Technology, Department of Fiber and Polymer Technology, KTH Royal Institute of Technology, Teknikringen 56-58, 100 44 Stockholm, Sweden.ORCID 0000-0001-7433-0350
Taras KaravayevCommodity Science and Customs Affairs Department, State University of Trade and Economics, Kyoto St., 19, 02156 Kyiv, Ukraine.ORCID 0000-0003-4429-2474
Oleksiy MyronyukDepartment of Chemical Technology of Composite Materials, Chemical Technology Faculty, Igor Sikorsky Kyiv Polytechnic Institute, Beresteiskyi Ave. 37, 03056 Kyiv, Ukraine.ORCID 0000-0003-0499-9491

Funding

Ministry of Education and Science of Ukraine PH/53-2024 (26.09.2024)Swedish Institute nr 00237/2025
6 · The paper itself

Abstract

This work presents an approach to water-dispersible polylactide (PLA) particle fabrication and their application in low-temperature film formation using a combination of mechanical dispersion and ultrasonication techniques. Stable PLA dispersions were obtained after removal of surfactant and allowed for thin-film preparation, exhibiting a significantly reduced minimum film formation temperature (MFFT) from 128 °C to 80 °C after reducing the characteristic particle size from ~2.2 µm to ~140 nm. To tailor the interfacial behavior and mechanical flexibility of the resulting coatings, a set of conventional and bio-based plasticizers was evaluated, including epoxidized fatty acids, PEG-400, and several hydrophobic deep eutectic solvents (HDESs) synthesized from menthol and carboxylic acids. Compatibility between PLA and each plasticizer was predicted using Hansen solubility parameters. The efficiency of plasticization was assessed through glass transition temperature suppression in solvent-cast films. The combination of submicron PLA particles and selected plasticizers enabled film formation at temperatures as low as 48 °C, confirming the potential of these systems for energy-efficient coating technologies. Furthermore, composite coatings incorporating micro-sized cellulose fibers (L/D ≈ 10.5-11.5) regenerated from agricultural residues were successfully obtained, demonstrating the feasibility of integrating bio-derived fillers into waterborne PLA formulations. In this study, the use of water-insoluble deep eutectic solvents type plasticizers for PLA coatings from water dispersions was reported for the first time. This establishes a foundation for developing sustainable, low-VOC, and low film formation temperature PLA-based coating materials.

Indexed as

coatingglass transition temperaturepolylactidepolymerpolymer filmwater dispersion coatings

Identifiers

PMID41599450
PMCPMC12846101

What OpenQuestion holds

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LicenceCC BY
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.