ArticleMembranes2025
Fabrication of Microphase-Separated Tröger's Base Polymer Membranes for Oxygen Enrichment.
Article in Membranes, 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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9 authors.
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Abstract
Tröger's base (TB) polymers have received increasing attention as a novel class of polymers with intrinsic microporosity, particularly for applications in gas separation. In this study, TB was quaternized with hydrophobic long chains to create a microphase-separated structure to enhance gas separation performance. On one hand, the tertiary amine structure of TB enabled facile grafting modification through the Menshutkin reaction. On the other hand, microphase-separated channels were created in the quaternized Tröger's base (QTB) membrane due to the polarity differences between the hydrophilicity of the quaternary ammonium groups and hydrophobicity of iodoalkanes, providing channels for gas transport within the membrane and thereby improving permeability selectivity. The successful synthesis of QTB membranes was confirmed by FTIR and
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