ArticleGels (Basel, Switzerland)2026
Impact of Gel-Derived Morphology-Controlled UiO-66/Cellulose Nanofiber Composite Separators on the Performance of Aqueous Zinc-Ion Batteries.
Article in Gels (Basel, Switzerland), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Zinc dendrite growth and side reactions remain critical challenges hindering the advancement of aqueous zinc-ion batteries (AZIBs). This study proposes a gel-based strategy for designing high-performance separators by regulating the crystal morphology of the metal-organic framework UiO-66 within a cellulose nanofiber (CNF) gel matrix. The resulting gel-derived separators exhibit distinctive structural and interfacial properties that significantly enhance battery performance. Compared with hierarchical porous structures (H-UiO-66), the octahedral morphology (O-UiO-66) disperses more uniformly in the CNF gel network, forming well-defined ion transport channels through its integrated gel architecture. The fabricated O-UiO-66/CNF gel separator demonstrates exceptional hydrophilicity (contact angle 21°), high porosity (73.2%), and significantly improved zinc ion migration number (0.72). Electrochemical tests reveal that this gel-based separator effectively guides uniform zinc deposition while suppressing dendrite growth. Zn/Zn symmetric cells using the O-UiO-66/CNF gel separator achieve a cycle life exceeding 800 h at 1 mA cm
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