Evidence map›Paper›PMID 41585563›Full record

ArticleFood chemistry: X2026

Synthesis-free and high-efficient molecular complexation based magnetic dispersive liquid-liquid microextraction for the efficient enrichment and determination of phenoxycarboxylic acid herbicide in various samples.

Wenchao Han, Xinyue Wang, Tingting Zhang, Fengchao Wang, Zixin Zhang, Di Chen, Lifeng Han, Guozheng Li, Liming Wang

Abstract read
In one paragraph

Article in Food chemistry: X, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Wenchao HanDepartment of Pharmacy, the 7th People's Hospital of Zhengzhou, Zhengzhou 450016, China.
Xinyue WangState Key Laboratory of Component-Based Chinese Medicine, Tianjin Key Laboratory of TCM Chemistry and Analysis, Haihe Laboratory of Modern Chinese Medicine, Tianjin University of Traditional Chinese Medicine, 10 Poyanghu Road, Jinghai District, Tianjin 301617, PR China.
Tingting ZhangState Key Laboratory of Component-Based Chinese Medicine, Tianjin Key Laboratory of TCM Chemistry and Analysis, Haihe Laboratory of Modern Chinese Medicine, Tianjin University of Traditional Chinese Medicine, 10 Poyanghu Road, Jinghai District, Tianjin 301617, PR China.
Fengchao WangState Key Laboratory of Component-Based Chinese Medicine, Tianjin Key Laboratory of TCM Chemistry and Analysis, Haihe Laboratory of Modern Chinese Medicine, Tianjin University of Traditional Chinese Medicine, 10 Poyanghu Road, Jinghai District, Tianjin 301617, PR China.
Zixin ZhangState Key Laboratory of Component-Based Chinese Medicine, Tianjin Key Laboratory of TCM Chemistry and Analysis, Haihe Laboratory of Modern Chinese Medicine, Tianjin University of Traditional Chinese Medicine, 10 Poyanghu Road, Jinghai District, Tianjin 301617, PR China.
Di ChenZhengzhou Research Base, State Key Laboratory of Cotton Bio-breeding and Integrated Utilization, Henan Key Laboratory of Nanomedicine for Targeting Diagnosis and Treatment, School of Pharmaceutical Sciences, Zhengzhou University, Zhengzhou 450001, China.
Lifeng HanState Key Laboratory of Component-Based Chinese Medicine, Tianjin Key Laboratory of TCM Chemistry and Analysis, Haihe Laboratory of Modern Chinese Medicine, Tianjin University of Traditional Chinese Medicine, 10 Poyanghu Road, Jinghai District, Tianjin 301617, PR China.
Guozheng LiDepartment of Classical Chinese Medicine, The Second Affiliated Hospital of Tianjin University of Traditional Chinese Medicine, Tianjin 300250, China.
Liming WangState Key Laboratory of Component-Based Chinese Medicine, Tianjin Key Laboratory of TCM Chemistry and Analysis, Haihe Laboratory of Modern Chinese Medicine, Tianjin University of Traditional Chinese Medicine, 10 Poyanghu Road, Jinghai District, Tianjin 301617, PR China.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

This study developed a molecular complexation-based dispersive liquid-liquid microextraction combined with magnetic particle-assisted extractant retrieval technology (MC-DLLME-MPAR) for the efficient detection of phenoxycarboxylic acid herbicide (PCA) residues in fruits, vegetables, and herbal plants. The proposed method utilized tri-n-butyl phosphate (TBP) as the extractant for molecular complexation, which could selectively enrich the target polar compounds through hydrogen bonding, and employed magnetic particles for the rapid retrieval, with a sample preparation time of only 5 min. Coupled with HPLC-UV analysis, the method showed good linearity, limits of detection (LODs) and quantification (LOQs), respectively. Methodological validation demonstrated both high sensitivity and stability. Green assessment tools were used for evaluation of the green degree and the results indicated that this method significantly reduced environmental impact. Compared to existing technologies, the developed method is synthesis-free, cost-effective, and straightforward, providing a reliable solution for high-throughput monitoring of PCA residues in complex matrices.

Indexed as

Agricultural-related productsDispersive liquid-liquid microextractionHPLC-UVMC-DLLME-MPARMolecular complexationPCA

Identifiers

PMID41585563
PMCPMC12828733

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.