ArticleACS nano2026
Guest-Induced Large and Tunable Negative Thermal Expansion in Soft Microporous Carbon.
Article in ACS nano, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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6 authors.
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Abstract
Materials that exhibit negative thermal expansion (NTE) are of fundamental interest due to their rarity and counterintuitive behavior. While research in this area has been directed toward the discovery of materials that display NTE and explaining its origin, there has been less attention to describing the complexities of a secondary phase or other guests that could influence the magnitude and mechanism of NTE. We report herein that zeolite-templated carbon (ZTC), a soft carbonaceous framework solid with ordered microporosity, exhibits a large and widely tunable thermal expansion in the presence of adsorbed guests. For ZTC in the presence of CO
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