ArticleACS applied materials & interfaces2026
Stacking Order-Mediated Spin-State Modulation in Iron Phthalocyanine Covalent Organic Frameworks Enables Efficient Oxygen Reduction Reaction.
Article in ACS applied materials & interfaces, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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11 authors.
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Abstract
Covalent organic frameworks (COFs) such as iron phthalocyanine (FePc) have been considered as potential electrocatalysts. Herein, we provide important insights into modulating the intrinsic activity of FePc COFs for the oxygen reduction reaction (ORR) by adjusting their stacking configuration. The eclipsed, AA-stacked and the staggered, AB-stacked FePc COF configurations were obtained via adjusting the interlayer interaction forces. Electrochemical studies reveal that the AA-stacked FePc COF exhibits a half-wave potential of 0.856 V vs RHE, which is 0.195 V higher than that of the AB-stacked FePc COF. The assembled zinc-air battery, using AA-stacked FePc COF as the cathode, demonstrates a high cell voltage of 1.64 V vs Zn
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