ArticleACS sustainable chemistry & engineering2026
Synthesis of Pellet-Based Pd/C Egg-Shell Catalysts for Reversible Hydrogen Storage in Formate/Bicarbonate.
Article in ACS sustainable chemistry & engineering, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
We report the scalable synthesis of egg-shell Pd/C pellet catalysts for the reversible formate/bicarbonate hydrogen-storage cycle. This system is inherently safe, nontoxic and allows for the easy control of hydrogen storage and release through pressure or temperature. A simple synthesis protocol with oxalic acid as a chelating additive furnishes a uniform and thin Pd shell. The optimized catalyst is active in both half-reactions, delivering hydrogen release rates up to 17.4 L h
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