ArticleOrganic letters2026
Pentafluoroethyl Sulfoximine Reagent for the Photocatalytic Pentafluoroethylation-Difunctionalization of Styrene Derivatives.
Article in Organic letters, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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7 authors.
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Abstract
We herein describe the synthesis of a pentafluoroethyl sulfoximine and its application in the pentafluoroethylation-difunctionalization of styrene derivatives. This sulfoximine reagent acts as a source of pentafluoroethyl radical to react with styrenes under mild photocatalytic conditions. By using simple nucleophiles, the pentafluoroethyl group can be introduced to styrenes with concomitant formation of C-O/C-N/C-S/C-C bonds, which significantly broadens the difunctionalization scope involving pentafluoroethylation compared to previous copper-based methods.
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