ArticleOrganic letters2026
Electron Donor-Acceptor Chromophore Assembly as an Enabling Process for the Overall Light-Driven Reduction of Phosphine Oxides.
Article in Organic letters, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Phosphines make up one of the largest classes of organophosphorus compounds, with applications in academic research and industry. Their preparation from phosphine oxides is mechanistically and thermodynamically highly challenging but opens the possibility for phosphorus recycling. We show that phosphine oxides can be converted into their corresponding phosphonium salts and subsequently reduced in a light-driven reaction to obtain the desired phosphines in 40-80% overall yields in a one-pot procedure. The reported methodology is free of exogenously added photocatalysts and utilizes the
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