ArticleChemistry (Weinheim an der Bergstrasse, Germany)2026
Polydopamine-Mediated Grafting of Cationic Polymer Brushes for Adsorption of Fluorinated Compounds.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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10 authors.
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Abstract
Understanding the adsorption behavior of charged molecular species at functionalized polymer interfaces is critical for advancing surface science and material design. Building upon recent advances in polydopamine (PDA)-mediated polymer grafting, we investigated electrostatic adsorption at cationic polymer brush surfaces. Using a grafting-to approach, we covalently attached poly(2-trimethylammonioethyl methacrylate chloride) (PTMAEMA) to PDA-coated stonewool fibers and characterized the resulting charged interface via x-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and thermogravimetric analysis (TGA). We employed perfluorooctanoic acid (PFOA) as a model anionic adsorbate to investigate binding at a quaternary amine-functionalized surface. Batch equilibrium sorption studies revealed concentration-dependent adsorption kinetics, achieving three times higher binding affinity for PTMAEMA-functionalized fibers at concentrations ranging from 0.5 to 5.0 g L
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