ArticleACS materials Au2026
Ratiometric Mechano-Fluorescent Elastomers Dually Promoted via Effective Force-Triggered Radicals and Preeminent Toughnesses/Stretchabilities by Unconventional Shuttling Dimensions of Tetraphenylethylene-Suspended [c2] Daisy Chain Rotaxanes.
Article in ACS materials Au, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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10 authors.
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Abstract
Innovative radical-type mechano-fluorescent polyurethane (PU) elastomers were developed by integrating axle- and macrocycle-exerted force modes of tetraphenylethylene (TPE)-functionalized daisy chain rotaxanes with expanded/contracted conformations into polymer matrices, revealing distinct mechanical and optical performances under external tensile forces. Surprisingly, the designed PU films containing negligible amounts (0.02% molar ratio of all monomers) of daisy chain structures with unconventional shuttling dimensions (as artificial molecular muscle tougheners) exhibited ultrastretchable capabilities and preeminent toughnesses, possessing a record-high toughness of 1363 MJ/m
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