ArticleAdvanced materials (Deerfield Beach, Fla.)2026
On-Surface Synthesis of Bismuth Monolayers through Ice-Confined Redox Reactions.
Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
2D bismuth possesses a unique combination of properties, such as cryogenic-free quantum spin Hall effects and intrinsic single-element ferroelectricity, making it highly promising for next-generation electronic devices. However, the synthesis of 2D bismuth via exfoliation or direct growth is hindered by the low structural anisotropy of bulk bismuth crystals. To address this challenge, we demonstrate an unprecedented ice-confined bottom-up strategy for growing 2D bismuth. This approach involves kinetically controlled nucleation in liquid nitrogen (-196 °C), followed by redox-driven anisotropic growth within the confined space between ice and aluminum surfaces at -20 °C. The surfactant-free process yields solution-processable crystalline 2D bismuth with micrometer-scale lateral dimensions and atomic-level thickness, where 72% of the sheets are 1-3 layers thick. Thanks to its oxophilic surfaces, the as-grown 2D bismuth effectively captures CO
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