ArticleNature communications2026
Cluster level entropy enhancement in neutral acetate electrolytes enables economical and durable zinc air batteries.
Article in Nature communications, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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1 citing paper in PubMed.
- Cluster level entropy enhancement in neutral acetate electrolytes enables economical and durable zinc air batteries.Nature communications · 2026Article
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10 authors.
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Abstract
Neutral zinc-air batteries provide a viable alternative to alkaline systems by avoiding salt creep and carbonate passivation. Among candidate electrolytes, acetate-based formulations are particularly attractive for their low cost, sustainability, and compatibility with ambient-air operation. However, their widespread adoption is limited by a trade-off between two concentration regimes. Dilute electrolytes trigger side reactions and lack ionic strength, while concentrated ones suffer from kinetic limitations due to contact ion pair clustering. Here, we propose a cluster-level entropy enhancement strategy that optimizes the mesoscopic configuration of the electrolyte by disrupting large clusters in concentrated acetate electrolytes. This entropy enhancement improves zinc ion diffusivity and kinetics, mitigates interfacial concentration gradients, and maintains local ionic strength for fast electrochemical reactions, as evidenced by various synchrotron X-ray techniques and theoretical simulations. Consequently, the zinc-air batteries in neutral electrolyte deliver over 1800 hours at 0.1 mA cm
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