Anti-Thermal-Quenching Phosphors Based on Metal Halides.

Thermal quenching (TQ) generally occurs in phosphors and is ascribed to the activation of nonradiative transitions at elevated temperatures. This effect limits the use of most phosphors in high-power/high-temperature applications, such as outdoor lighting and laser systems. To achieve anti-TQ properties, structural design of phosphors is required. This usually follows two guidelines: (1) increasing lattice rigidity to minimize thermal expansion; (2) converting thermal energy into radiative transitions to compensate for the nonradiative losses. While metal oxides and metal nitrides dominate the field of commercial anti-TQ phosphors, metal halides, despite their inherently soft lattices, have shown remarkable progress as anti-TQ phosphors in recent years. Here, we review the advances in anti-TQ metal halides (covering the time span from 2017, when the first reports appeared, until today) and discuss their mechanisms and applications. We argue that the low synthesis temperatures of metal halides and their high photoluminescence quantum yields (PLQYs) make them promising candidates as anti-TQ phosphors. Furthermore, since the rich optical-physical processes underlying the anti-TQ effect in soft-lattice in metal halides are only now beginning to be unraveled, this creates opportunities for many fundamental investigations.