ArticleOrganic letters2026
Ligand-Enabled Photocatalytic Reactivity of Iron(III) Halide Salts with Cyan and Green Light.
Article in Organic letters, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Iron(III) halide salts have emerged as cheap and efficient catalysts for photocatalytic transformations, including C-H alkylation, C-H and alkene oxidation, azidation/amination, and others. The majority of these methods require UV light (λ ≤ 390 nm), and systematic efforts to enable the use of lower-energy visible light remain valuable. We report the use of simple Fe(III) salts that enable C-H functionalizations with longer wavelength visible light up to 525 nm (green light). The one-pot conversion of aldehydes to amides, esters, and ketones as well as direct alkylation are described using blue, cyan, and green light.
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