[Fabrication of high-degradation-efficiency molecularly imprinted photocatalysts and its selective degradation performance].

Molecularly imprinted photocatalysts （MIPCs）， which integrate specific molecular recognition with photocatalytic degradation capabilities， hold great promise for the selective and efficient removal of trace pollutants from complex environmental matrices. However， conventional surface-imprinting layers coated on photocatalysts often cause light-shielding effects， thereby reducing the photocatalytic efficiency of MIPCs. To overcome this limitation， the present study proposes a heterojunction-based interfacial in-situ imprinting strategy. In this approach， molecular imprinting cavities are directly constructed at the interface of composite photocatalysts. This design not only avoids the negative impact of surface shielding but also facilitates interfacial charge transfer， thus achieving a synergistic enhancement of both molecular recognition selectivity and photocatalytic efficiency. Based on this concept， a highly efficient molecularly imprinted photocatalyst， BiOBr-Cu/ppyr-MIPs， was successfully fabricated. The synthesis utilized surface molecular imprinting technology with the organic pollutant acid orange （AO） as the template molecule， and BiOBr-Cu/polypyrrole （ppyr） composite as the heterojunction matrix. Polypyrrole， introduced as a conductive polymer， served as the imprinting layer that promotes charge migration. The synthesis conditions， including monomer amount and polymerization time， were systematically optimized to maximize imprinting efficiency and photocatalytic performance. The obtained BiOBr-Cu/ppyr-MIPs were comprehensively characterized. Scanning electron microscopy （SEM） revealed a well-defined morphology with uniformly distributed imprinted layers. X-ray diffraction （XRD） analysis confirmed that the introduction of the polypyrrole-based imprinting layer did not significantly alter the crystal structure of the BiOBr-Cu composite. Fourier-transform infrared spectroscopy （FTIR） showed characteristic peaks attributable to the pyrrole ring， such as C-H in-plane bending， C-H stretching， and C=N stretching vibrations， indicating successful incorporation of the polypyrrole framework. X-ray photoelectron spectroscopy （XPS） further confirmed the formation of the imprinted layer， with increased proportions of C-N and O=C bonding components observed in the C 1