Evidence map›Paper›PMID 41528855›Full record

ArticleJournal of the American Chemical Society2026

Positional Isomerization of 1,2-Azaborine through BN-Benzvalene.

Tomoya Ozaki, Skylar Diamandis, Nina Rybansky, Xinyu Yang, Fan Bai, Bo Li, Jier Huang, Shih-Yuan Liu

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. A Catalyst-Controlled Divergent Rearomatization of BN-Benzvalene.Journal of the American Chemical Society · 2026
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Tomoya OzakiDepartment of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, United States.
Skylar DiamandisDepartment of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, United States.
Nina RybanskyDepartment of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, United States.
Xinyu YangDepartment of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, United States.
Fan BaiDepartment of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, United States.
Bo LiDepartment of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, United States.
Jier HuangDepartment of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, United States.ORCID 0000-0002-2885-5786
Shih-Yuan LiuDepartment of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, United States.ORCID 0000-0003-3148-9147

Funding

Expanding the Chemical and Functional Space with Boron-Nitrogen HeterocyclesR35GM153328 · NIGMS · BOSTON COLLEGE · PI Shih-Yuan Liu · 2024 to 2026
$1.3M
Bruker D8 VENTURE DiffractometerS10OD030360 · OD · BOSTON COLLEGE · PI LI, BO · 2022 to 2022
$428k
NIGMS NIH HHS R35 GM153328NIH HHS S10 OD030360
6 · The paper itself

Abstract

A photochemical positional isomerization approach for converting readily accessible C5-aryl-1,2-azaborines into their C4-aryl counterparts via a BN-benzvalene intermediate is described. The oxidative radical cation pathway from BN-benzvalene to the C4-aryl products is supported by deuterium labeling experiments, transient absorption (TA) spectroscopy, and DFT calculations. The reaction's utility is demonstrated by providing the first general method to C4,C5-difunctionalized 1,2-azaborines and the regioselective synthesis of hexa-substituted derivatives.

Identifiers

PMID41528855
PMCPMC13290377

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.