Evidence map›Paper›PMID 41524343›Full record

ArticleJournal of the American Chemical Society2026

Characterization of a Silver Vinylcarbene Intermediate in Carbene-Alkyne Metathesis and Its Concerted C(sp

Àlex Díaz-Jiménez, Roger Monreal-Corona, Arijit Saha, Andrea Álvarez-Núñez, Anna Company, Teodor Parella, Pedro J Pérez, Ana Caballero, Anna Roglans, Albert Poater and 1 more

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Àlex Díaz-JiménezInstitut de Química Computacional i Catàlisi (IQCC) and Departament de Química, Universitat de Girona (UdG), Facultat de Ciències, C/Maria Aurèlia Capmany, 69, Girona 17003, Catalunya, Spain.ORCID 0000-0003-1241-8263
Roger Monreal-CoronaInstitut de Química Computacional i Catàlisi (IQCC) and Departament de Química, Universitat de Girona (UdG), Facultat de Ciències, C/Maria Aurèlia Capmany, 69, Girona 17003, Catalunya, Spain.ORCID 0000-0003-3071-9887
Arijit SahaInstitut de Química Computacional i Catàlisi (IQCC) and Departament de Química, Universitat de Girona (UdG), Facultat de Ciències, C/Maria Aurèlia Capmany, 69, Girona 17003, Catalunya, Spain.ORCID 0000-0003-1354-814X
Andrea Álvarez-NúñezInstitut de Química Computacional i Catàlisi (IQCC) and Departament de Química, Universitat de Girona (UdG), Facultat de Ciències, C/Maria Aurèlia Capmany, 69, Girona 17003, Catalunya, Spain.
Anna CompanyInstitut de Química Computacional i Catàlisi (IQCC) and Departament de Química, Universitat de Girona (UdG), Facultat de Ciències, C/Maria Aurèlia Capmany, 69, Girona 17003, Catalunya, Spain.ORCID 0000-0003-4845-4418
Teodor ParellaServei de Ressonància Magnètica Nuclear, Facultat de Ciències i Biociències, Universitat Autònoma de Barcelona, Cerdanyola del Vallès 08193, Catalunya, Spain.ORCID 0000-0002-1914-2709
Pedro J PérezLaboratorio de Catálisis Homogénea, Unidad Asociada al CSIC, CIQSO-Centro de Investigación en Química Sostenible and Departamento de Química, Universidad de Huelva, Huelva 21007, Spain.ORCID 0000-0002-6899-4641
Ana CaballeroLaboratorio de Catálisis Homogénea, Unidad Asociada al CSIC, CIQSO-Centro de Investigación en Química Sostenible and Departamento de Química, Universidad de Huelva, Huelva 21007, Spain.ORCID 0000-0001-7846-6183
Anna RoglansInstitut de Química Computacional i Catàlisi (IQCC) and Departament de Química, Universitat de Girona (UdG), Facultat de Ciències, C/Maria Aurèlia Capmany, 69, Girona 17003, Catalunya, Spain.ORCID 0000-0002-7943-5706
Albert PoaterInstitut de Química Computacional i Catàlisi (IQCC) and Departament de Química, Universitat de Girona (UdG), Facultat de Ciències, C/Maria Aurèlia Capmany, 69, Girona 17003, Catalunya, Spain.ORCID 0000-0002-8997-2599
Anna Pla-QuintanaInstitut de Química Computacional i Catàlisi (IQCC) and Departament de Química, Universitat de Girona (UdG), Facultat de Ciències, C/Maria Aurèlia Capmany, 69, Girona 17003, Catalunya, Spain.ORCID 0000-0003-2545-9048

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Herein we present compelling evidence of the intervention of electrophilic silver vinylcarbenes in the carbene-alkyne metathesis (CAM) reaction, leading to a pivotal C(sp

Identifiers

PMID41524343
PMCPMC12856905

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.