ArticleCrystal growth & design2026
Eyring-Polanyi Rate Theory for the Homogeneous Nucleation of Organic Crystals from Solution.
Article in Crystal growth & design, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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2 citing papers in PubMed.
- Article
- A DFT investigation on the chemisorption mechanism and coordinate bonding of chromium by polyphenol-silica composites: insights from NCI and QTAIM analyses.Journal of molecular modeling · 2026Article
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1 author.
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Abstract
Using elementary concepts of chemical reaction kinetics, the rates of primary homogeneous organic crystal nucleation from supersaturated solutions are modeled as nucleation with first order kinetics from large solute density fluctuations (LSDFs). Solute density fluctuations are modeled as diffusively driven many-body collisions of weakly interacting solvated solute molecules. The first order rate constant is a system-specific supersaturation-independent rate constant for nucleation in LSDFs. It is shown for several solute-solvent systems that the temperature-dependence of this nucleation rate constant exhibits Arrhenius behavior. The activation enthalpy (Δ
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