ArticleMolecules (Basel, Switzerland)2025
On the Mechanism of Random Handedness Generation in the Reactions of Heterocyclic Aldehydes with Diallylboronates.
Article in Molecules (Basel, Switzerland), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The mechanism of generation of products with opposite handedness in the reactions of heterocyclic aldehydes with diallylboronates was studied by NMR experiments and DFT computations. The origin of this unusual phenomenon is a competition between monomeric and dimeric autoinductors that promote the formation of opposite enantiomers. Thus, NMR data suggest that racemic alcohol
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