ArticleMolecules (Basel, Switzerland)2025
The Evaluation of Eutectic Solvents as Catalysts for Mediating the Greener Synthesis of Poly(alkylene 2,5-furandicarboxylate)s.
Article in Molecules (Basel, Switzerland), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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1 citing paper in PubMed.
- Green Synthesis of Ca-Doped ZnO Nanosheets with Tunable Band Structure via Cactus-Juice-Mediated Coprecipitation for Enhanced Photocatalytic HMolecules (Basel, Switzerland) · 2026Article
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4 authors.
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Abstract
In a quest to develop more sustainable polymers, decoupling their production from fuel-based resources and searching for alternative greener synthetic pathways are important priorities. Among the numerous polymers that fall into this category are furan-based polyesters. Besides the origin of polymers, their synthesis is another critical topic to consider regarding the overall greenness of the final product. However, despite several studies focusing on bio-based alternatives, such as poly(alkylene 2,5-furandicarboxylate)s, their synthesis still relies on air- and water-sensitive metal-based catalysts and is typically carried out under harsh conditions. This study explores an alternative approach with the application of eutectic solvents (ES) as catalysts for a more sustainable approach for synthesising furan-based polyesters, specifically poly(ethylene 2,5-furandicarboxylate) (PEF), as well as poly(trimethylene furandicarboxylate) (PTF) and poly(butylene furandicarboxylate) (PBF). Two different ES were evaluated as catalysts; the best results were obtained with urea and zinc acetate ES (U:Zn(OAc)
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