ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2026
Ionic Highways under Multivariate-Coupled Strategies: Ultrahigh Power Generation from Industrial Waste Liquors Using Robust COF Membranes.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Efficiently harvesting the intrinsic energy from low-grade heat, acidity, and high salinity of desulfurization waste liquors is crucial for sustainable management, yet remains challenging due to the instability of conventional membranes under such extreme multi-physics conditions. Herein, we report a high-performance osmotic energy conversion device engineered via a multivariate coupling strategy. The core of this device is a robust membrane based on β-ketoenamine-linked covalent organic frameworks (COFs), featuring nanochannels functionalized with tailored stimuli-responsive groups to dynamically regulate surface charge density. The β-ketoenamine linkage endows exceptional membrane stability, enabling durable operation under coupled thermal, chemical, and electrochemical stresses. Experimental and computational studies demonstrate that the remarkable power enhancement stems not only from acid-induced protonation that boosts charge density, but also from the utilization of low-grade heat to accelerate ion transport. By simulating the multi-physical field coupling in real waste liquors, the device achieves an ultrahigh power output of 258.81 W m
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