ArticleProceedings of the National Academy of Sciences of the United States of America2026
Mechanisms of the viscosity decrease and increase of aqueous CsCl.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Aqueous salt solutions occur in many aspects of chemistry, biology, and geology. Increasing the concentration of most aqueous salt solutions increases the viscosities. In contrast, adding CsCl to water initially decreases the viscosity, but at moderate concentration further addition increases it. While this phenomenon is well known, the molecular mechanisms for the reduction and increase have not been elucidated. We used ultrafast optical heterodyne-detected optical Kerr effect (OHD-OKE) and IR pump-probe experiments, as well as density functional theory to investigate the impact of Cs
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