ArticleAngewandte Chemie (International ed. in English)2026
Benzoyl-Xanthenoxanthenes: Versatile Chromophores for Light-Engaging Applications.
Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Pyrazine-embedded N^N^N-chelating tetracoordinate organoboron polycyclic heteroaromatics with low-lying LUMO levels and near-infrared luminescence.Chemical science · 2026Article
- Benzoyl-Xanthenoxanthenes: Versatile Chromophores for Light-Engaging Applications.Angewandte Chemie (International ed. in English) · 2026Article
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11 authors.
Funding
Abstract
In this work, we present a modular donor-acceptor strategy that produces oxidatively stable, benzoyl-fused peri-xanthenoxanthene (PXX) ribbons with near-infrared (NIR) emission and light-harvesting properties. Benzoyl fusion at the pseudo-peri positions, achieved through intramolecular Friedel-Crafts planarization, creates the first benzoyl-functionalized PXX monomers, dimers, and trimers that exhibit deep red-NIR absorption and emission without significantly raising the HOMO level. The ribbons display strong, tunable absorption and fluorescence bands, with up to 63% of emission in the NIR and an NIR fluorescence quantum yield reaching 0.36 in solution. Lewis adducts formed between boron-based Lewis acids and carbonyl acceptor sites further enhance the electron-accepting nature of the ketones, producing pure NIR emission (
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