Evidence map›Paper›PMID 41502367›Full record

ArticleJournal of the American Chemical Society2026

Redox-Switchable Halogen Bonding in Haloanthracene Mediators Enables Efficient Electrocatalytic C-N Coupling.

Atsuki Hirama, Kayo Suda, Shohei Yoshinaga, Moto Kikuchi, Su-Gi Chong, Azusa Kikuchi, Yusuke Ishigaki, Daisuke Yokogawa, Mahito Atobe, Naoki Shida

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Atsuki HiramaDepartment of Chemistry and Life Science, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan.
Kayo SudaGraduate School of Arts and Sciences, The University of Tokyo, Komaba, Meguro-ku, Tokyo 153-8902, Japan.ORCID 0000-0002-4717-7159
Shohei YoshinagaDepartment of Chemistry and Life Science, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan.
Moto KikuchiDepartment of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060-0810, Japan.
Su-Gi ChongInstitute of Advanced Sciences, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan.
Azusa KikuchiDepartment of Chemistry and Life Science, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan.
Yusuke IshigakiDepartment of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060-0810, Japan.ORCID 0000-0001-7961-3595
Daisuke YokogawaGraduate School of Arts and Sciences, The University of Tokyo, Komaba, Meguro-ku, Tokyo 153-8902, Japan.
Mahito AtobeDepartment of Chemistry and Life Science, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan.ORCID 0000-0002-3173-3608
Naoki ShidaDepartment of Chemistry and Life Science, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan.ORCID 0000-0003-0586-1216

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

We report the development of redox mediators based on 9-halo-10-arylanthracenes that engage in halogen bonding only upon one-electron oxidation. This redox-switchable interaction enables an effective substrate preorganization and promotes intramolecular C-N bond formation via electrocatalysis. Systematic evaluation of halogenated mediators (

Identifiers

PMID41502367
PMCPMC12921847

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.