ArticleACS electrochemistry2026
Quaternary Ammonium Additives as Dual Inhibitors of Hydrogen Evolution and Cathodic Corrosion in Aqueous Electrosynthesis.
Article in ACS electrochemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
In organic electrosynthesis, the hydrogen evolution reaction (HER) is a parasitic process that significantly diminishes the faradaic efficiency (FE) of aqueous electrochemical reductions and contributes to the cathodic corrosion of widely used metals such as lead and tin. Developing strategies that selectively suppress HER without hindering desired electrochemical transformations is therefore crucial. In this study, we demonstrate that various quaternary ammonium salts (QAS) suppress HER on lead cathodes even under acidic conditions (pH 1). These QAS electrostatically self-assemble at the negatively charged lead surface, forming a cationic barrier that hinders hydronium ion (H
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